Metal free photooxidation of alkyl bis(catecholato)silicates with the organic dye 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyano-benzene (4CzIPN) allows the smooth formation of alkyl radicals. The latter can be efficiently engaged either with radical acceptors to provide homolytic addition products or in photoredox/nickel dual catalysis reactions to obtain cross-coupling products.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c6cc04636c | DOI Listing |
Publication Analysis
Top Keywords
dual catalysis
8
organic photoredox
4
photoredox catalysis
4
catalysis oxidation
4
oxidation silicates
4
silicates applications
4
applications radical
4
radical synthesis
4
synthesis dual
4
catalysis metal
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!