Heretofore only observed in living systems, we report that weak-field ion cyclotron resonance (ICR) also occurs in inanimate matter. Weak magnetic field (50 nT) hydronium ICR at the field combination (7.84 Hz, 7.5 µT) markedly changes water structure, as evidenced by finding an altered index of refraction exactly at this combined field. This observation utilizes a novel technique which measures the scattering of a He-Ne laser beam as the sample is exposed to a ramped magnetic field frequency. In addition to the hydronium resonance, we find evidence of ICR coupling to a more massive structure, possibly a tetrahedral combination of three waters and a single hydronium ion. To check our observations, we extended this technique to DO, successfully predicting the specific ICR charge-to-mass ratio for DO that alters the index of refraction.
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http://dx.doi.org/10.1080/15368378.2016.1181082 | DOI Listing |
J Am Chem Soc
September 2024
Leibniz Institute for Solid State and Materials Research (IFW Dresden), Helmholtzstrasse 20, 01069 Dresden, Germany.
Our knowledge about endohedral metallofullerenes (EMFs) is restricted to the structures with sufficient kinetic stability to be extracted from the arc-discharge soot and processed by chromatographic and structural techniques. For the most abundant rare-earth monometallofullerene M@C, experimental studies repeatedly demonstrated (9) and (6) carbon cage isomers, while computations predicted equal stability of the "missing" (8) isomer. Here we report that this isomer is indeed formed but has not been recovered from soot using standard protocols.
View Article and Find Full Text PDFJ Am Chem Soc
July 2024
Department of Chemistry, Tulane University, New Orleans, Louisiana 70118, United States.
The iron-molybdenum cofactor of nitrogenase (FeMoco) catalyzes fixation of N via Fe hydride intermediates. Our understanding of these species has relied heavily on the characterization of well-defined 3d metal hydride complexes, which serve as putative spectroscopic models. Although the Fe ions in FeMoco, a weak-field cluster, are expected to adopt locally high-spin Fe configurations, synthetically accessible hydride complexes featuring d or d electron counts are almost exclusively low-spin.
View Article and Find Full Text PDFSoft Matter
March 2024
Department of Mathematics, National Institute of Technology Durgapur, Durgapur-713209, India.
The present article deals with the electrohydrodynamic motion of diffuse porous particles governed by an applied DC electric field. The spatial distribution of monomers as well as the charge distribution across the particle are considered to follow sigmoidal distribution involving decay length. Such a parameter measures the degree of inhomogeneity of the monomer distribution across the particle.
View Article and Find Full Text PDFPhys Chem Chem Phys
September 2023
Graduate School of Science, Nagoya University, Furo-cho, Chikusa, Nagoya, Aichi, 464-8602, Japan.
Directional fragment ejection from a tetrahedral molecule CH in linearly polarized two-color ( and 2) asymmetric intense laser fields (50 fs, 1.4 × 10 W cm, 800 nm and 400 nm) has been studied by three-dimensional ion coincidence momentum imaging. The H fragment produced from dissociative ionization, CH → H + CH + e, is preferentially ejected on the larger amplitude side of the laser electric fields.
View Article and Find Full Text PDFPhys Chem Chem Phys
April 2023
Centre of New Technologies, University of Warsaw, ul. Banacha 2c, 02-097 Warszawa, Poland.
Three new crystalline phases of the borohydride complex, [-BuN][RE(BH)] (RE = Gd (1), GdY (2) and GdY (3)), were obtained in pure form and characterised using EPR spectroscopy and AC/DC magnetometry. In all 1-3, unusually slow field-induced magnetic relaxation was observed up to high temperatures, which above 10 K is dominated by power law thermal dependence identified as the two-phonon Raman process. Therefore, weak-field ligands such as borohydride seem to be the perfect candidates for triggering slow magnetic relaxation of magnetically isotropic gadolinium(III) ions.
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