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Anderson-like alkoxo-polyoxovanadate clusters serving as unprecedented second building units to construct metal-organic polyhedra. | LitMetric

Anderson-like alkoxo-polyoxovanadate clusters serving as unprecedented second building units to construct metal-organic polyhedra.

Chem Commun (Camb)

Institute of Functional Material Chemistry, Local United Engineering Lab for Power Battery, Northeast Normal University, Changchun, 130024 Jilin, People's Republic of China.

Published: August 2016

AI Article Synopsis

Article Abstract

Unprecedented Anderson-like alkoxo-polyoxovanadate [V6O6(OCH3)9(μ6-SO4)(COO)3](2-) polyanions can serve as 3-connected second building units (SBUs) that assemble with dicarboxylate or tricarboxylate ligands to form a new family of metal organic tetrahedrons of V4E6 and V4F4 type (V = vertex, E = edge, and F = face). To our knowledge, this alkoxo-polyoxovanadate-based SBU is the first ever reported.

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Source
http://dx.doi.org/10.1039/c6cc04583aDOI Listing

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