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Fluorescence sensor for sequential detection of zinc and phosphate ions. | LitMetric

Fluorescence sensor for sequential detection of zinc and phosphate ions.

Spectrochim Acta A Mol Biomol Spectrosc

Department of Applied Chemistry, Kyungpook National University, Daegu 41566, Republic of Korea. Electronic address:

Published: December 2016

AI Article Synopsis

Article Abstract

A new, highly selective turn-on fluorescent chemosensor based on 2-(2'-tosylamidophenyl)thiazole (1) for the detection of zinc and phosphate ions in ethanol was synthesized and characterized. Sensor 1 showed a high selectivity for zinc compared to other cations and sequentially detected hydrogen pyrophosphate and hydrogen phosphate. The fluorescence mechanism can be explained by two different mechanisms: (i) the inhibition of excited-state intramolecular proton transfer (ESIPT) and (ii) chelation-induced enhanced fluorescence by binding with Zn(2+). The sequential detection of phosphate anions was achieved by the quenching and subsequent revival of ESIPT.

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http://dx.doi.org/10.1016/j.saa.2016.06.026DOI Listing

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