AI Article Synopsis

  • The study utilizes Q-band and X-band pulsed electron paramagnetic resonance (EPR) spectroscopy to analyze six nitroxide radicals formed from borane-phosphane frustrated Lewis pairs (FLPs), focusing on their anisotropic interactions.
  • Previous X-band continuous-wave EPR measurements mainly captured hyperfine coupling with 14N and 31P, but the current study employs ESEEM and HYSCORE techniques to enhance the understanding of 11B interactions, supported by temperature-dependent analysis.
  • The findings at Q-band frequency (34 GHz) yield more precise measurements of g-tensor components and hyperfine interaction parameters, resulting in high-accuracy data for EPR spin Hamiltonian parameters of the FLP

Article Abstract

Q-band and X-band pulsed electron paramagnetic resonance spectroscopic methods (EPR) in the solid state were employed to refine the parameters characterizing the anisotropic interactions present in six nitroxide radicals prepared by N,N addition of NO to various borane-phosphane frustrated Lewis pairs (FLPs). The EPR spectra are characterized by the g-anisotropy as well as by nuclear hyperfine coupling between the unpaired electron and the 11B/10B, 14N and 31P nuclear magnetic moments. It was previously shown that continuous-wave spectra measured at X-band frequency (9.5 GHz) are dominated by the magnetic hyperfine coupling to 14N and 31P, whereas the g-tensor values and the 11B hyperfine coupling parameters cannot be refined with high precision from lineshape fitting. On the other hand, the X-band electron spin echo envelope modulation (ESEEM) and hyperfine sublevel correlation (HYSCORE) spectra are completely dominated by the nuclear hyperfine coupling to the 11B nuclei, allowing a selective determination of their interaction parameters. In the present work this analysis has been further validated by temperature dependent ESEEM measurements. In addition, pulsed EPR data measured in the Q-band (34 GHz) are reported, which present an entirely different situation: the g-tensor components can be measured with much higher precision, and the ESEEM and HYSCORE spectra contain information about all of the 10B, 11B, 14N and 31P hyperfine interaction parameters. Based on these new results, we report here high-accuracy and precision data of the EPR spin Hamiltonian parameters measured on six FLP-NO radical species embedded in their corresponding hydroxylamine host structures. While the ESEEM spectra at Q-band frequency turn out to be very complex (due to the multinuclear contribution to the overall signal) in the HYSCORE experiment the extension over two dimensions renders a better discrimination between the different nuclear species, and the signals arising from hyperfine coupling to 10B, 11B, 14N and 31P nuclei can be individually analyzed.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4918942PMC
http://journals.plos.org/plosone/article?id=10.1371/journal.pone.0157944PLOS

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