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The Complex Valorization of Black Alder Bark Biomass in Compositions of Rigid Polyurethane Foam.
Materials (Basel)
December 2024
Latvian State Institute of Wood Chemistry, Dzerbenes Street 27, LV-1006 Riga, Latvia.
The use of black alder (BA) bark biomass in rigid polyurethane (PUR) foam compositions was the main task of investigation. Extractive compounds isolated from the bark through hot water extraction were used as precursors for bio-polyol synthesis via acid-free liquefaction with the polyether polyol Lupranol 3300 and through oxypropylation with propylene carbonate. The OH functionality and composition of the polyols were analyzed via wet chemistry and FTIR spectroscopy.
View Article and Find Full Text PDFSulfur chains glass formed by fast compression.
Nat Commun
January 2025
Center for High Pressure Science and Technology Advanced Research, Beijing, 100093, China.
Due to the sulfur's atoms' propensity to form molecules and/or polymeric chains of various sizes and configuration, elemental sulfur possesses more allotropes and polymorphs than any other element at ambient conditions. This variability of the starting building blocks is partially responsible for its rich and fascinating phase diagram, with pressure and temperature changing the states of sulfur from insulating molecular rings and chains to semiconducting low- and high-density amorphous configurations to incommensurate superconducting metallic atomic phase. Here, using a fast compression technique, we demonstrate that the rapid pressurisation of liquid sulfur can effectively break the molecular ring structure, forming a glassy polymeric state of pure-chain molecules (Am-S).
View Article and Find Full Text PDFToward Green Liquid Nitrogen Fertilizer Synthesis: Plasma-Driven Nitrogen Oxidation and Partial Electrocatalytic Reduction.
Adv Sci (Weinh)
December 2024
State Key Laboratory of Electrical Insulation and Power Equipment, Centre for Plasma Biomedicine, Xi'an Jiaotong University, Xi'an, 710049, P. R. China.
Liquid fertilizers, particularly when integrated with precision irrigation systems, offer a more efficient and sustainable alternative to traditional solid nitrogen fertilizers. The industrial production of ammonium nitrate (NHNO) is environmentally detrimental due to its reliance on fossil fuels. This study introduces an innovative air-to-NOx-to-NHNO pathway for synthesizing liquid nitrogen fertilizer.
View Article and Find Full Text PDFCoupling-Controlled Photonic Topological Ring Array.
ACS Photonics
December 2024
School of Information Science and Technology, ShanghaiTech University, Shanghai 201210, China.
Photonic topological insulators with boundary states present a robust solution to mitigate structure imperfections. By alteration of the virtual boundary between trivial and topological insulators, it is possible to bypass such defects. Coupled resonator optical waveguides (CROWs) have demonstrated their utility in realizing photonic topological insulators, as they exhibit distinct topological phases and band structures.
View Article and Find Full Text PDFThe Use of Recycled Cement-Bonded Particle Board Waste in the Development of Lightweight Biocomposites.
Materials (Basel)
December 2024
Institute of Sustainable Building Materials and Engineering Systems, Faculty of Civil and Mechanical Engineering, Riga Technical University, Kipsalas Str. 6A, LV-1048 Riga, Latvia.
Cement-bonded particle boards are gaining popularity globally due to their durability, strength, and, more importantly, environmental sustainability. The increasing demand for these materials has also created the necessity for the sustainable recycling of these materials. In this study, the potential to recycle wood-wool cement board (WWCB) waste into new lightweight insulation biocomposite material was examined.
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