Room-temperature multiferroism in LuFeO3 (LFO) films is demonstrated by exploiting the orthorhombic-hexagonal (o-h) morphotrophic phase coexistence. The LFO film further reveals a magnetoelectric coupling effect that is not shown in single-phase (h- or o-) LFO. The observed multiferroism is attributed to the combination of sufficient polarization from h-LFO and net magnetization from o-LFO.
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http://dx.doi.org/10.1002/adma.201601989 | DOI Listing |
Materials (Basel)
November 2024
Center of Physics of Minho and Porto Universities (CF-UM-UP), Laboratory for Materials and Emergent Technologies (LaPMET), Departamento de Física, Universidade do Minho, Campus de Gualtar, 4710-057 Braga, Portugal.
Laser ablation was used to successfully fabricate multiferroic bilayer thin films, composed of BaTiO (BTO) and CoFeO (CFO), on highly doped (100) Si substrates. This study investigates the influence of BaTiO layer thickness (50-220 nm) on the films' structural, magnetic, and dielectric properties. The dense, polycrystalline films exhibited a tetragonal BaTiO phase and a cubic spinel CoFeO layer.
View Article and Find Full Text PDFDalton Trans
December 2024
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nangjing University, Nanjing, China.
Magnetoelectric (ME) coupling refers to the interaction between electric and magnetic orders in materials. Based on ME coupling, the phenomenon that an external magnetic field induces electric polarization and an external electric field induces change in mangetization can be observed and is referred to as the ME effect. Examples of the ME effect include magnetodielectric (MD), magnetoferroelectric (MF), magnetoresistence (MR) and electrically controlled magnetism effects.
View Article and Find Full Text PDFNanomaterials (Basel)
September 2024
Faculty of Physics, Sofia University "St. Kliment Ohridski", J. Bouchier Blvd. 5, 1164 Sofia, Bulgaria.
Using a microscopic model and Green's function theory, we have investigated the co-doping effect on ferroelectric KNbO nanoparticles. Let us emphasize that while the doping with transition metal ions at the Nb site leads an increase in the ferromagnetism and a reduction the band gap, it also decreases the ferroelectricity. On the other hand, doping with La or Ba at the K site leads to enhanced polarization, but does not lead to the appearance of ferromagnetism and reduction in the band gap.
View Article and Find Full Text PDFAdv Mater
November 2024
School of Mechanical Engineering, Sungkyunkwan University, Suwon, 16419, South Korea.
Recently, researchers have been investigating artificial ferroelectricity, which arises when inversion symmetry is broken in certain R-stacked, i.e., zero-degree twisted, van der Waals (vdW) bilayers.
View Article and Find Full Text PDFNanoscale
October 2024
School of Physical Science and Technology, Southwest University, Chongqing 400715, China.
Two-dimensional room-temperature Janus ferrovalley semiconductors with valley polarization and piezoelectric polarization offer new perspectives for designing multifunctional nanodevices. Herein, using first-principles calculations, we predict that the Janus 2H-ZrTeI monolayer is an intrinsic ferromagnetic semiconductor with in-plane magnetic anisotropy and a Curie temperature of 111 K. The Janus ZrTeI monolayer possesses a significant valley polarization of 141 meV due to time-reversal and inversion symmetry breaking.
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