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m-Xylylenediaminium sulfate: crystal structure and Hirshfeld surface analysis. | LitMetric

m-Xylylenediaminium sulfate: crystal structure and Hirshfeld surface analysis.

Acta Crystallogr E Crystallogr Commun

Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte, Université de Carthage, Tunisia.

Published: June 2016

The crystal structure of the title salt {systematic name: [1,3-phenyl-enebis(methyl-ene)]bis-(aza-nium) sulfate}, C8H14N2 (2+)·SO4 (2-), consists of infinite (100) sheets of alternating organic and inorganic entities The m-xylylenediaminium cations are linked to the sulfate anions by N-H⋯O and asymmetric bifurcated N-H⋯(O,O) hydrogen bonds, generating a three-dimensional network. A weak C-H⋯O inter-action also occurs. The Hirshfeld surface analysis and the two-dimensional fingerprint maps indicate that the packing is dominated by H⋯O/O⋯H and H⋯H contacts.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4908557PMC
http://dx.doi.org/10.1107/S2056989016006940DOI Listing

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