Developing ingenious heterostructure photoelectrodes in photoelectrochemical (PEC) cells to both harvest more solar photons and steer desired charge separation flow is a prerequisite challenge for PEC water splitting. Herein a hierarchical p-Si/n-ZnO@Au heterostructure was constructed via large-area growth of one-dimensional (1D) ZnO nanorod arrays (NRAs) on p-Si substrate followed by decorating with Au nanoparticles (NPs), which exhibited remarkably improved photocathode activity for PEC water splitting relative to the bare Si and Si/ZnO NRAs photocathodes. In addition to structural superiorities of 1D NRAs, a series of dynamic contributions from complementary band-gap structure, p-n heterojunctions and Au plasmon towards photon harvesting and charge separation were demonstrated to ensure a well-steered collection of photoelectrons at the exposed ZnO nanorods and Au NPs, enabling substantially improved photocathode performance.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1088/0957-4484/27/30/305403 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Design and synthesis of autogenous growth NiFe bimetallic phosphide catalysts on a nickel iron foam-like substrate for efficient overall water splitting.
J Colloid Interface Sci
January 2025
Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province, School of Resources and Materials, Northeastern University at Qinhuangdao, Qinhuangdao 066004, PR China. Electronic address:
The design of low-cost, highly active, and stable electrocatalysts is pivotal for advancing water electrolysis technologies. In this study, carbonyl iron powder (CIP) was anchored within the pores of nickel foam (NF) by electroplating nickel, creating nickel iron foam-like (NFF-L) substrates. Subsequently, nickel-iron hydroxide (NiFe-OH) was synthesized on the NFF-L substrate employing an autogenous growth strategy, followed by a phosphating treatment that produced a nanoflower-like NiFe bimetallic phosphide heterostructure catalyst (FeP-NiP@NFF-L).
View Article and Find Full Text PDFAtomic Gap-State Engineering of MoS for Alkaline Water and Seawater Splitting.
ACS Nano
January 2025
Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore.
Transition-metal dichalcogenides (TMDs), such as molybdenum disulfide (MoS), have emerged as a generation of nonprecious catalysts for the hydrogen evolution reaction (HER), largely due to their theoretical hydrogen adsorption energy close to that of platinum. However, efforts to activate the basal planes of TMDs have primarily centered around strategies such as introducing numerous atomic vacancies, creating vacancy-heteroatom complexes, or applying significant strain, especially for acidic media. These approaches, while potentially effective, present substantial challenges in practical large-scale deployment.
View Article and Find Full Text PDFThe Power of Movement: Linking Physical Activity with Nutritional Health and Blood Sugar Balance in a Dalmatian Type 2 Diabetic Population.
Nutrients
January 2025
Internal Medicine Department, School of Medicine, University of Split, 21000 Split, Croatia.
Background And Objectives: Regular physical activity (PA) and Mediterranean diet (MeDi) adherence independently improve glycemic control and clinical outcomes in type 2 diabetes mellitus (T2DM). This study examined the associations between PA, body composition (BC), MeDi adherence, and glycemic control in Dalmatian T2DM patients.
Materials And Methods: A cross-sectional study was conducted at the University Hospital of Split (November-December 2023) during an open call for T2DM patients.
Investigation of Chloride Salt Erosion on Asphalt Binders and Mixtures: Performance Evaluation and Correlation Analysis.
Materials (Basel)
January 2025
College of Engineering, Zhejiang Normal University, Jinhua 321004, China.
Asphalt pavement, widely utilized in transportation infrastructure due to its favourable properties, faces significant degradation from chloride salt erosion in coastal areas and winter deicing regions. In this study, two commonly used asphalt binders, 70# base asphalt and SBS (Styrene-Butadiene-Styrene)-modified asphalt, were utilized to study the chloride salt erosion effect on asphalt pavement by immersing materials in laboratory-prepared chloride salt solutions. The conventional properties and adhesion of asphalt were assessed using penetration, softening point, ductility, and pull-off tests, while Fourier transform infrared spectroscopy (FTIR) elucidated the erosion mechanism.
View Article and Find Full Text PDFStudy on the Properties of Basalt Fiber-Calcined Gangue-Silty Clay Foam Concrete for Filling Undermined Goaf Areas of Highways.
Materials (Basel)
December 2024
College of Water Resources and Construction Engineering, Shihezi University, Shihezi 832000, China.
The collapse of surface goaf beneath highways can result in instability and damage to roadbeds. However, filling the goaf areas with foam concrete can significantly enhance the stability of the roadbeds while considerably reducing the costs of filling materials. This study analyzes the effects on destructive characteristics, mechanical properties, stress-strain curve features, and relevant metrics, while also observing the microstructure of basalt fiber-calcined gangue-silty clay foam concrete (BF-CCG-SCFC).
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!