Catalytic dehydrocoupling of amine-boranes and amines into diaminoboranes: isolation of a Pt(ii), Shimoi-type, η(1)-BH complex.

Chem Commun (Camb)

Instituto de Investigaciones Químicas (IIQ), Departamento de Química Inorgánica, Centro de Innovación en Química Avanzada (ORFEO-CINCA), CSIC and Universidad de Sevilla, Avda. Américo Vespucio 49, 41092 Sevilla, Spain.

Published: June 2016

The platinum complex [Pt(I(t)Bu')(I(t)Bu)][BAr(F)] is a very efficient catalyst in the synthesis of diaminoboranes through dehydrocoupling of amine-boranes and amines. Shimoi-type, η(1)-BH complexes are key intermediates in the process.

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Source
http://dx.doi.org/10.1039/c6cc02720bDOI Listing

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