The platinum complex [Pt(I(t)Bu')(I(t)Bu)][BAr(F)] is a very efficient catalyst in the synthesis of diaminoboranes through dehydrocoupling of amine-boranes and amines. Shimoi-type, η(1)-BH complexes are key intermediates in the process.
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http://dx.doi.org/10.1039/c6cc02720b | DOI Listing |
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