The Low Background Infrared calibration (LBIR) facility at the National Institute of Standards and Technology (NIST) presently maintains four absolute cryogenic radiometers (ACRs) which serve as standard reference detectors for infrared calibrations performed by the facility. The primary standard for optical power measurements at NIST-Gaithersburg has been the High Accuracy Cryogenic Radiometer (HACR). Recently, an improved radiometer, the Primary Optical Watt Radiometer (POWR), has replaced the HACR as the primary standard. In this paper, we present the results of comparisons between the radiometric powers measured by the four ACRs presently maintained by the LBIR facility to that measured by the HACR and POWR. This was done by using a Si photodiode light-trapping detector as a secondary transfer standard to compare the primary national standards to the ACRs maintained by the LBIR facility. The technique used to compare an ACR to the trap detector is described in detail. The absolute optical power measurements are found to be within 0.1 % of the primary standard for all the ACRs examined in this study.
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http://dx.doi.org/10.6028/jres.111.024 | DOI Listing |
Nat Commun
December 2024
Key Laboratory of Molecular Nanostructure and Nanotechnology, Beijing National Laboratory for Molecular Sciences, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, China.
Zn-air batteries (ZABs) present high energy density and high safety but suffer from low oxygen reaction reversibility and dendrite growth at Zn electrode in alkaline electrolytes. Non-alkaline electrolytes have been considered recently for improving the interfacial processes in ZABs. However, the dynamic evolution and reaction mechanisms regulated by electrolytes at both the positive and Zn negative electrodes remain elusive.
View Article and Find Full Text PDFPhotochem Photobiol
December 2024
Institute of Chemistry, State University of Campinas, Campinas, São Paulo, Brazil.
Given that non-equilibrium molecular motion in thermal gradients is influenced by both solute and solvent, the application of spectroscopic methods that probe each component in a binary mixture can provide insights into the molecular mechanisms of thermal diffusion for a large class of systems. In the present work, we use an all-optical setup whereby near-infrared excitation of the solvent leads to a steady-state thermal gradient in solution, followed by characterization of the non-equilibrium system with electronic spectroscopy, imaging, and intensity. Using rhodamine B in water as a case study, we perform measurements as a function of solute concentration, temperature, wavelength, time, near-infrared laser power, visible excitation wavelength, and isotope effect.
View Article and Find Full Text PDFJ Phys Chem Lett
December 2024
Department of Chemistry, Graduate School of Science, Osaka Metropolitan University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan.
Optical vortices possess a helical phase wavefront with central phase dislocation and orbital angular momentum. We demonstrated three-dimensional microstructure formation using a femtosecond optical vortex beam. Two-photon polymerization of photocurable resin was induced by long-term exposure, resulting in the fabrication of cylindrical structures.
View Article and Find Full Text PDFFront Psychol
December 2024
School of Mental Health, Wenzhou Medical University, Wenzhou, Zhejiang, China.
Background: Trypophobia refers to the visual discomfort (e.g., disgust or anxiety) experienced by some people when viewing clusters of bumps or holes.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
December 2024
School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Jilin Provincial Science and Technology Innovation Center of Optical Materials and Chemistry, Jilin Provincial International Joint Research Center of Photo-functional Materials and Chemistry, Changchun 130022, China; State Key Laboratory of Supramolecular Structure and Materials, Institute of Theoretical Chemistry, College of Chemistry, Jilin University, Changchun 130021, China. Electronic address:
The power conversion efficiency (PCE) of ternary all-small-molecule organic solar cells (T-ASM-OSCs) differs significantly from that of the polymer systems (2 %), and the role of third component remains unclear. The electron donor of coumarin derivatives with simple structure and strong and broad light absorption has high PCE for T-ASM-OSCs composed of non-fullerene acceptors (Y6 and DBTBT-IC). Here, we calculated the electronic structure and interfacial properties of the binary C1-CN:Y6 and ternary C1-CN:Y6:DBTBT-IC systems using molecular dynamic (MD) simulations and density functional theory (DFT) to explore the role of the third component (DBTBT-IC).
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