Photoredox/nickel dual catalysis via single electron transmetalation allows coupling of Csp(3)-Csp(2) hybridized centers under mild conditions. A procedure for the coupling of electron-deficient aryl triflates, -tosylates, and -mesylates with alkylbis(catecholato)silicates is presented. This method represents the first example of the use of phenol derivatives as electrophilic coupling partners in photoredox/nickel dual catalysis.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4994714 | PMC |
| http://dx.doi.org/10.1021/acs.joc.6b00800 | DOI Listing |
Publication Analysis
Top Keywords
photoredox/nickel dual
12
dual catalysis
12
phenol derivatives
8
coupling partners
8
coupling
4
derivatives coupling
4
partners alkylsilicates
4
alkylsilicates photoredox/nickel
4
catalysis photoredox/nickel
4
catalysis single
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!