AI Article Synopsis
- Organobismuthines are valuable organometallic compounds derived from low-cost, nontoxic bismuth salts.
- Triarylbismuthines stand out for their stability in air and moisture, as well as their ability to tolerate various functional groups.
- This study focuses on creating highly functionalized triarylbismuth reagents through a method involving the manipulation of three functional groups, demonstrating their application in palladium- and copper-catalyzed reactions for arylation of carbon, nitrogen, and oxygen.
Article Abstract
Organobismuthines are an attractive class of organometallic reagents that can be accessed from inexpensive and nontoxic bismuth salts. Triarylbismuthines are particularly interesting due to their air and moisture stability and high functional group tolerance. We report herein a detailed study on the preparation of highly functionalized triarylbismuth reagents by triple functional group manipulation and their use in palladium- and copper-catalyzed C-, N-, and O-arylation reactions.
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| http://dx.doi.org/10.1021/acs.joc.6b00767 | DOI Listing |
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