This work presents the photocatalytic degradation of the pharmaceutical drug clofibric acid in a fixed-bed reactor filled with TiO-coated glass rings. Experiments were carried out under UV radiation. A kinetic model that takes into account radiation absorption by means of the local surface rate of photon absorption (LSRPA) has been developed. The LSRPA was obtained from the results of a radiation model. The Monte Carlo method was employed to solve the radiation model, where the interaction between photons and TiO-coated rings was considered. Data from experiments carried out with rings with different numbers of catalyst coatings and different irradiation levels were used to estimate the parameters of the kinetic model. A satisfactory agreement was obtained between model simulations and experimental results.
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http://dx.doi.org/10.1007/s11356-016-6855-2 | DOI Listing |
Int J Mol Sci
December 2024
Joint International Research Laboratory of Information Display and Visualization, School of Electronic Science and Engineering, Southeast University, Nanjing 210096, China.
This study presents a facile one-pot synthesis method to fabricate BiFeO-BiFeO-BiO heterojunction photocatalysts with controllable compositions and pure phases. Three different binary heterojunctions (BiFeO/BiFeO, BiFeO/BiO, and BiFeO/BiO) and a ternary BiFeO/BiFeO/BiO heterojunction were formed, all exhibiting significantly enhanced photocatalytic performance for the degradation of methylene blue (MB) and phenol under visible light irradiation, outperforming the individual compositions. Notably, the BiFeO/BiFeO heterojunction achieved the highest degradation efficiency (93.
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January 2025
School of Environment, South China Normal University, Guangzhou 510006, China.
The development of efficient and sustainable photocatalysts for wastewater treatment remains a critical challenge in environmental remediation. In this study, a ternary photocatalyst, Cu-CuO/g-CN, was synthesized by embedding copper-copper oxide heterostructural nanocrystals onto g-CN nanosheets via a simple deposition method. Structural and optical characterization confirmed the successful formation of the heterostructure, which combines the narrow bandgap of CuO, the high stability of g-CN, and the surface plasmon resonance (SPR) effect of Cu nanoparticles.
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December 2024
Chair for Integrated Systems and Photonics, Department of Electrical and Information Engineering, Faculty of Engineering, Kiel University, Kaiserstr. 2, 24143 Kiel, Germany.
Biological neural circuits are based on the interplay of excitatory and inhibitory events to achieve functionality. Axons form long-range information highways in neural circuits. Axon pruning, i.
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December 2024
Department of Chemical Engineering Materials Environment, Sapienza University of Rome, Via del Castro Laurenziano 7, 00161 Rome, Italy.
Paper-based artworks are prone to natural aging processes driven by chemical and biological processes. Numerous treatments have been developed to mitigate deterioration and prevent irreversible damage. In this study, we investigated the use of poly(acrylic acid)/TiO composite hydrogels, combining their cleaning and protective functions in a minimally invasive treatment.
View Article and Find Full Text PDFEnviron Res
January 2025
Jiangxi Province Key Laboratory of Surface Engineering,Jiangxi Science & Technology Normal University, Nanchang 330013, PR China; School of Materials and Energy, Jiangxi Science & Technology Normal University, Nanchang 330013, P. R. China. Electronic address:
One-dimensional (1D) hierarchical photocatalyst has the advantages of 1D materials and hierarchical materials, which is a kind of potential high performance photocatalytic materials. However, how to efficiently synthesize 1D hierarchical BiOBr is still a huge challenge. Herein, 1D rod-like BiO(OH)(NO)·3HO, the hydrolysis product of Bi(NO)·5HO, was acted as both the template and Bi source to synthesize 1D hierarchical hollow BiOBr (1DHHBr) through a facile solution stirring method at room temperature, using KBr as Br source.
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