AI Article Synopsis
- The research focuses on the reversible hetero-Diels-Alder reaction involving 1,2-oxazines made from a peralkylcyclopentadiene and various nitrosocarbonyl dienophiles.
- It highlights that different dienophiles can significantly change the dynamic properties of the oxazine products.
- The study suggests potential uses in creating dynamic covalent materials or systems for delivering small molecules due to the reactions' reliability and sensitivity to temperature and moisture.
Article Abstract
We have investigated the reversible hetero-Diels-Alder reaction of 1,2-oxazines derived from a peralkylcyclopentadiene and a series of nitrosocarbonyl dienophiles. The nature of the dienophile was found to impart broad tunability to the dynamic character of the oxazine adducts. The reversibility was also observed in polymeric systems. The fidelity of the reaction and tunable sensitivity toward elevated temperature and water signify potential applications in the development of dynamic covalent materials or delivery systems for small molecule payloads.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c6ob00400h | DOI Listing |
Publication Analysis
Top Keywords
12-oxazines derived
8
derived peralkylcyclopentadiene
8
investigation dynamic
4
dynamic nature
4
nature 12-oxazines
4
peralkylcyclopentadiene nitrosocarbonyl
4
nitrosocarbonyl species
4
species investigated
4
investigated reversible
4
reversible hetero-diels-alder
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!