Band overlap and random noise are a serious problem in infrared spectra, especially for aging spectrometers. In this paper, we have presented a simple method for spectrum restoration. The proposed method is based on local operations, and involves sparse decompositions of each spectrum piece under an evolving overcomplete dictionary, and a simple averaging calculation. The content of the dictionary is of prime importance for the deconvolution process. Quantitative assessments of this technique on simulated and real spectra show significant improvements over the state-of-the-art methods. The proposed method can almost eliminate the effects of instrument aging. The features of these deconvoluted infrared spectra are more easily extracted, aiding the interpretation of unknown chemical mixtures.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1364/AO.55.002813 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Structural, morphological and biological assessment of magnetic hydroxyapatite with superior hyperthermia potential for orthopedic applications.
Sci Rep
January 2025
Department of Chemistry, School of Advanced Sciences, Vellore Institute of Technology, Vellore, Tamil Nadu, 632014, India.
Hydroxyapatite (HA) is an important constituent of natural bone. The properties of HA can be enhanced with the help of various ionic substitutions in the crystal lattice of HA. Iron (Fe) is a vital element present in bones and teeth.
View Article and Find Full Text PDFMicrobial Biodegradation of Synthetic Polyethylene and Polyurethane Polymers by Pedospheric Microbes: Towards Sustainable Environmental Management.
Polymers (Basel)
January 2025
Institute of Environmental Sciences, Hungarian University of Agriculture and Life Sciences, Páter Károly u. 1, H-2100 Gödöllő, Hungary.
This study attempted to isolate and identify pedospheric microbes originating in dumpsites and utilized them for the degradation of selected synthetic polymers for the first time in a cost-effective, ecologically favorable and sustainable manner. Specifically, low-density polyethylene (LDPE) and polyurethane (PUR) were converted by the isolated fungi, i.e.
View Article and Find Full Text PDFCompact Quantum Cascade Laser-Based Noninvasive Glucose Sensor Upgraded with Direct Comb Data-Mining.
Sensors (Basel)
January 2025
Shunde Innovation School, University of Science and Technology Beijing, Foshan 528399, China.
Mid-infrared spectral analysis has long been recognized as the most accurate noninvasive blood glucose measurement method, yet no practical compact mid-infrared blood glucose sensor has ever passed the accuracy benchmark set by the USA Food and Drug Administration (FDA): to substitute for the finger-pricking glucometers in the market, a new sensor must first show that 95% of their glucose measurements have errors below 15% of these glucometers. Although recent innovative exploitations of the well-established Fourier-transform infrared (FTIR) spectroscopy have reached such FDA accuracy benchmarks, an FTIR spectrometer is too bulky. The advancements of quantum cascade lasers (QCLs) can lead to FTIR spectrometers of reduced size, but compact QCL-based noninvasive blood glucose sensors are not yet available.
View Article and Find Full Text PDFAchieving a Near-Infrared Absorption by A-DA'D-A Type Isoindigo-Based Small Molecular Acceptors for Organic Photovoltaics.
Molecules
January 2025
School of Metallurgical and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China.
Isoindigo (IID)-based non-fullerene acceptors, known for their broad absorption spectra and high charge carrier mobilities, play a crucial role in organic photovoltaics. In this study, two A-DA'D-A type unfused ring acceptors (URAs), IDC8CP-IC and IDC6CP-IC, were designed and synthesized using cyclopentadithiophene (CPDT) and IID core units, each functionalized with different alkyl chains (2-hexyldecyl and 2-octyldodecyl), through an atom- and step-efficient direct C-H arylation (DACH) method. Both URAs, despite the absence of non-covalent conformation locking between CPDT and IID, demonstrated favorable molecular planarity, broad absorption ranges, low band gaps, and high molar absorption coefficients.
View Article and Find Full Text PDFThe Role of Polarizability in Isoelectronic Ions: The Case of Pseudohalides.
Molecules
January 2025
Department of Chemistry "Ugo Schiff" and CSGI, University of Florence, 50019 Sesto Fiorentino, Italy.
Specific ion effects are widespread and have been studied for over a century, yet they remain poorly understood. Terms like "kosmotropes" and "chaotropes" are convenient rules of thumb but the frequent reversal of the Hofmeister series implies their limitations. Polarizability is often used to classify ions, with kosmotropes considered low in polarizability and chaotropes high.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!