Knitting: Recently Antonchick and Manna described a unique annulation that knits together three acetophenones to construct cyclopropanes. The cascade is mediated by organocopper and free radical species, and amounts to the first known [1+1+1] cyclotrimerization. It works well for ketones having electron-deficient or electron-rich substituents in their aryl rings. DTBP=di-tert-butylperoxide.
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http://dx.doi.org/10.1002/anie.201602891 | DOI Listing |
PLoS One
December 2024
School of Economics and Management, Qingdao Agricultural University, Qingdao, Shandong Province, China.
In the context of the transformation of urban-rural dual economic structure, one of the important ways to realize urban-rural integrated development is to carry out county industrial structure upgrading. Based on the policy of returning home to start business as a quasi-natural experiment, this paper empirically analyzes the relationship between returning home to start business and upgrading of county industrial structure. Selecting 1997 counties across the country from 2000 to 2021 as the research sample, a multi-temporal double-difference model is used to test the impact of the place-based policy on county industrial structure and the mechanism of the impact, and the result confirms that the implementation of the pilot policy of returning home entrepreneurship plays a positive and obvious role in promoting the level of industrial development of county-level areas.
View Article and Find Full Text PDFMicrobiol Spectr
December 2024
College of Bioinformatics Science and Technology, Harbin Medical University, Harbin, Heilongjiang, China.
Unlabelled: SCovid v2.0 (http://bio-annotation.cn/scovid or http://bio-computing.
View Article and Find Full Text PDFNanoscale
December 2024
Institute of Circular Economy, College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, P. R. China.
Renewable electricity-powered electrooxidation of 5-hydroxymethylfurfural (HMFOR) to FDCA offers a green and sustainable approach to producing an essential monomer for bio-polymers, provided that a highly efficient electrocatalyst is present. Herein, we show that the doping of scandium (Sc) into an NiFe-LDH electrocatalyst (Sc-NiFe-LDH) considerably promotes HMFOR by enhancing the formation of high-valence Ni-O active sites, facilitating electron transport and HMF adsorption and suppressing the oxygen evolution reaction. In the presence of the Sc-NiFe-LDH electrocatalyst, an FDCA faradaic efficiency and selectivity of 96.
View Article and Find Full Text PDFJ Environ Manage
December 2024
School of Finance, Harbin University of Commerce, Harbin, 150028, China. Electronic address:
High carbon intensity (CI) contributes to climate change, hindering the achievement of the United Nations' Sustainable Development Goal 13 (SDG13). National legal commitments (LC) to reduce carbon emissions can mitigate this obstacle. This study identifies 32 countries with LC to carbon reduction as the treatment group and countries with commitments at other levels (e.
View Article and Find Full Text PDFJ Environ Manage
December 2024
School of Business and Dongwu Think Tank, Soochow University, Suzhou, Jiangsu, 215012, China. Electronic address:
The issue of whether smart city construction (SCC) can promote urban green development (UGD) is controversial. To address this problem, first, a UGD evaluation index system with four dimensions, namely, green production, green living, green growth, and green ecology, is developed in this study to measure the UGD level. Second, the causal relationship between SCC and UGD is examined by using a double machine learning model.
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