The demand for precious metals has increased in recent years. However, low concentrations of precious metals dissolved in wastewater are yet to be recovered because of high operation costs and technical problems. The unicellular red alga, Galdieria sulphuraria, efficiently absorbs precious metals through biosorption. In this study, over 90% of gold and palladium could be selectively recovered from aqua regia-based metal wastewater by using G. sulphuraria. These metals were eluted from the cells into ammonium solutions containing 0.2M ammonium salts without other contaminating metals. The use of G. sulphuraria is an eco-friendly and cost-effective way of recovering low concentrations of gold and palladium discarded in metal wastewater.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1016/j.biortech.2016.01.061 | DOI Listing |
EJNMMI Radiopharm Chem
December 2024
The Hevesy Laboratory, DTU Health Technology, Frederiksborgvej 399, 4000, Roskilde, Denmark.
Background: Brachytherapy (BT) is routinely used in the treatment of various cancers. Current BT relies on the placement of large sources of radioactivity at the tumor site, requiring applicators that may cause local traumas and lesions. Further, they suffer from inflexibility in where they can be placed and some sources reside permanently in the body, causing potential long-term discomfort.
View Article and Find Full Text PDFJ Am Chem Soc
December 2024
Instituto de Investigaciones Químicas (IIQ), Departamento de Química Inorgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Universidad de Sevilla and Consejo Superior de Investigaciones Científicas (CSIC). Avenida Américo Vespucio 49, 41092 Sevilla, Spain.
Bimetallic complexes have demonstrated a great ability to enhance the activity of monometallic systems for bond activation and catalysis. In this work, we explore the opposite approach: using a second metal to passivate the activity of another by reversible bimetallic inhibition. To do so we have synthesized a family of nine electrophilic gold complexes of formula Au(PR)(NTf) ([NTf] = [N(SOCF)]) that can act as inhibitors in the semihydrogenation of terminal and internal alkynes catalyzed by the iconic iridium Vaska complex IrCl(CO)(PPh).
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Department of Chemistry, University of Saskatchewan, 110 Science Place, Saskatoon S7N 5C9, SK, Canada. Electronic address:
Precious metal recovery from secondary sources has received significant attention due to the reduced availability of precious metals from conventional sources. Herein, chitosan (CHT) was modified via cross-linking with glutaraldehyde (glu) to yield CHT-glu adsorbents with improved physicochemical and adsorption properties with precious metal ions (Au(III) and Pd(II)). CHT-glu adsorbents were prepared at variable glu ratios and characterized via complementary spectral (IR, C solids NMR, XPS) and thermogravimetry methods.
View Article and Find Full Text PDFPharm Nanotechnol
December 2024
BIOMCI, Faculty of Medicine and Pharmacy of Agadir, University Ibn Zohr, Agadir, Morocco.
Nanotechnology is rapidly transforming various fields, including medicine, environmental conservation, agriculture, and pharmaceuticals. The production of metallic nanoparticles is a key area within this field, known for its innovative applications. However, traditional chemical and physical methods used for nanoparticle synthesis often involve toxic chemicals and are expensive, making them unsuitable for large-scale production.
View Article and Find Full Text PDFJ Mater Chem A Mater
December 2024
Materials Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University 3584 CG Utrecht The Netherlands
The catalytic and plasmonic properties of bimetallic gold-palladium (Au-Pd) nanoparticles (NPs) critically depend on the distribution of the Au and Pd atoms inside the nanoparticle bulk and at the surface. Under operating conditions, the atomic distribution is highly dynamic. Analyzing gas induced redistribution kinetics at operating temperatures is therefore key in designing and understanding the behavior of Au-Pd nanoparticles for applications in thermal and light-driven catalysis, but requires advanced characterization strategies.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!