Two enantiomers were observed by Scanning Tunneling Microscopy (STM) when meta-iodopyridine was physisorbed on a 4.6 K Cu(110) surface. The chirality of the reagent was retained in the products of the electron-induced reaction. Dynamical calculations showed this to be a consequence of the reaction occurring on one side of the mirror plane.
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http://dx.doi.org/10.1039/c6cc00849f | DOI Listing |
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