We report on ab initio no-core shell model calculations of the mirror Λ hypernuclei _{Λ}^{4}H and _{Λ}^{4}He, using the Bonn-Jülich leading-order chiral effective field theory hyperon-nucleon potentials plus a charge symmetry breaking Λ-Σ^{0} mixing vertex. In addition to reproducing rather well the 0_{g.s.}^{+} and 1_{exc}^{+} binding energies, these four-body calculations demonstrate for the first time that the observed charge symmetry breaking splitting of mirror levels, reaching hundreds of keV for 0_{g.s.}^{+}, can be reproduced using realistic theoretical interaction models, although with a non-negligible momentum cutoff dependence. Our results are discussed in relation to recent measurements of the _{Λ}^{4}H(0_{g.s.}^{+}) binding energy at the Mainz Microtron [A. Esser et al. (A1 Collaboration), Phys. Rev. Lett. 114, 232501 (2015)] and the _{Λ}^{4}He(1_{exc}^{+}) excitation energy [T.O. Yamamoto et al. (J-PARC E13 Collaboration), Phys. Rev. Lett. 115, 222501 (2015)].
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Chiral metal clusters, due to their intriguing optical properties and unique resemblance in size to biomolecules, have attracted a lot of attention in recent times as potential candidates for application in bio-detection and therapy. While several strategies are reported for the synthesis of optically active clusters, a facile approach that enhances a multitude of properties has remained a challenge. Herein, we report a simple strategy wherein the use of a chiral cationic surfactant, during the synthesis of achiral clusters, leads to the fabrication of chiral assemblies possessing enhanced luminescence and optical activity.
View Article and Find Full Text PDFPhys Rev Lett
December 2024
Institute for Advanced Study, Tsinghua University, Beijing 100084, China.
The nonintegrable higher spin Kitaev honeycomb model has an exact Z_{2} gauge structure, which exclusively identifies quantum spin liquid in the half-integer spin Kitaev model. But its constraints for the integer-spin Kitaev model are much limited, and even trivially gapped insulators cannot be excluded. The physical implications of exact Z_{2} gauge structure, especially Z_{2} fluxes, in integer-spin models remain largely unexplored.
View Article and Find Full Text PDFJ Phys Chem A
December 2024
Department of Chemistry, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada.
Aromatic organometallic complexes, such as ferrocene and the "inverse sandwich complex" [NaCp], are stabilized via charge-transfer (C-T) interactions and cation-π interactions (i.e., charge-induced dipole and charge-quadrupole interactions).
View Article and Find Full Text PDFACS Nano
December 2024
Department of Materials Science and Engineering, National University of Singapore, Singapore117575, Singapore.
A Rashba spin-splitting state with spin-momentum locking enables the charge-spin interconversion known as the Rashba effect, induced by the interplay of inversion symmetry breaking (ISB) and spin-orbit coupling (SOC). Enhancing spin-splitting strength is promising to achieve high spin-orbit torque (SOT) efficiency for low-power-consumption spintronic devices. However, the energy scale of natural ISB at the interface is relatively small, leading to the weak Rashba effect.
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December 2024
Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States.
Oxide superlattices reveal a rich array of emergent properties derived from the composition modulation and the resulting lattice distortion, charge transfer, and symmetry reduction that occur at the interfaces between the layers. The great majority of studies have focused on perovskite oxide superlattices, revealing, for example, the appearance of an interfacial 2D electron gas, magnetic moment, or improper ferroelectric polarization that is not present in the parent phases. Garnets possess greater structural complexity than perovskites: the cubic garnet unit cell contains 160 atoms with the cations distributed between three different coordination sites, and garnets exhibit a wide range of useful properties, including ferrimagnetism and ion transport.
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