Commercially available N-oxide (2-mercaptopyridine-N-oxide) is used as a ligand instead of an oxidizing agent to stabilize the compounds of main group elements in low-valent states. The isolated compounds [(C5H4NOS)2Sn (), (C5H4NOS)SnCl () and (C5H4NOS)GeCl ()] are the first structurally characterized examples of O,S-heterocyclic stannylenes and germylenes with interesting bonding features. Further, the reaction of compound with SbCl3 afforded the rare dichlorodiantimony oxide [{(C5H4NOS)SbCl}2O] () unprecedentedly.
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Article Synopsis
- A study was conducted on the reaction of dimethyl acetylene dicarboxylate (DMAD) with hypersilyl tetrylenes at room temperature, focusing on the compounds PhC(NBu)ESi(SiMe) where E = Ge (germanium) and Sn (tin).
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