The synthesis of an efficient precursor of the novel 1,7-naphthodiyne synthon is reported. Preliminary experiments demonstrate the usefulness of this platform for the synthesis of sterically congested polyarenes, such as helicenes and angularly fused acene derivatives. Furthermore, a novel intramolecular aryne trapping reaction is described.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1039/c6cc01214k | DOI Listing |
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!