Triphenylborane (BPh3 ) in highly polar, aprotic solvents catalyzes hydrosilylation of CO2 effectively under mild conditions to provide silyl formates with high chemoselectivity (>95 %) and without over-reduction. This system also promotes reductive hydrosilylation of tertiary amides as well as dehydrogenative coupling of silane with alcohols.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/chem.201601006 | DOI Listing |
Publication Analysis
Top Keywords
hydrosilylation co2
8
highly polar
8
polar aprotic
8
aprotic solvents
8
selective metal-free
4
metal-free hydrosilylation
4
co2 catalyzed
4
catalyzed triphenylborane
4
triphenylborane highly
4
solvents triphenylborane
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!