AI Article Synopsis
- Eudesmanolide farinosin, a naturally occurring compound, has been fully characterized for the first time since its isolation nearly 50 years ago.
- The initial assumptions about its stereochemistry and absolute configuration were confirmed using vibrational circular dichroism and Hooft X-ray evaluations.
- The molecular conformation of eudesmanolide is found to be quite similar in both gas and solid states.
Article Abstract
The naturally occurring eudesmanolide farinosin () is now fully characterized for the first time despite its original isolation almost half a century ago. The early assumed relative stereochemistry and absolute configuration were confirmed by vibrational circular dichroism together with evaluation of the Hooft X-ray parameters. The molecular conformation is very similar in the gas stage and in the solid state. Chirality 28:415-419, 2016. © 2016 Wiley Periodicals, Inc.
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| http://dx.doi.org/10.1002/chir.22595 | DOI Listing |
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