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Crystal structure of di-chlorido-bis-(dimethyl N-cyano-dithio-imino-carbonate)zinc. | LitMetric

Crystal structure of di-chlorido-bis-(dimethyl N-cyano-dithio-imino-carbonate)zinc.

Acta Crystallogr E Crystallogr Commun

Department of Chemistry and Biochemistry, University of Notre Dame, 246, Nieuwland, Science Hall, Notre Dame, IN 46557-5670, USA.

Published: March 2016

AI Article Synopsis

  • - The complex [ZnCl2(C4H6N2S2)2] features a Zn(II) atom coordinated in a distorted tetrahedral arrangement with two chloride (Cl) atoms and two nitrogen (N) atoms from dimethyl N-cyano-dithio-imino-carbonate ligands.
  • - The complex forms a crystalline structure where the molecules are linked via C-H⋯Cl hydrogen bonds and Cl⋯S interactions.
  • - This connectivity results in a two-dimensional arrangement of the complex that extends parallel to the ab plane in the crystal.

Article Abstract

The Zn(II) atom in the title complex, [ZnCl2(C4H6N2S2)2], is coordinated in a distorted tetra-hedral manner by two Cl atoms and two terminal N atoms of two dimethyl N-cyano-dithio-imino-carbonate ligands. In the crystal, the complex mol-ecules are connected through C-H⋯Cl hydrogen bonds and Cl⋯S contacts, leading to a two-dimensional structure extending parallel to the ab plane.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4778821PMC
http://dx.doi.org/10.1107/S2056989016002607DOI Listing

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