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Flow-dependent separation selectivity for organic molecules on metal-organic frameworks containing adsorbents. | LitMetric
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Flow-dependent separation selectivity for organic molecules on metal-organic frameworks containing adsorbents.

Anton Peristyy Pavel N Nesterenko Anita Das Deanna M D'Alessandro Emily F Hilder R Dario Arrua

Chem Commun (Camb)

Australian Centre for Research on Separation Science, University of Tasmania, Private Bag 75, Hobart, TAS 7001, Australia.

Published: April 2016

A new flow-dependent separation selectivity (FDSS) effect was discovered in isocratic HPLC. Significant changes in chromatographic selectivity were achieved by simple variation of the mobile phase flow rate. The FDSS effect was observed for a core-shell stationary phase using silica particles as a core and a Zr-based metal-organic framework (UiO-66) as a shell.

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 Source
http://dx.doi.org/10.1039/c6cc00111dDOI Listing

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