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Absolute line strength measurements of hydroperoxyl (HO2) radical in the OO-stretching (ν3) fundamental band have been performed by means of mid-infrared time-resolved dual-comb spectroscopy. By employing two sets of dual-comb spectrometers, high-resolution time-resolved spectra of HO2 and HCl, formed in the photolysis reaction system of Cl2/CH3OH/O2, could be, respectively, measured near 1123 and 3059 cm-1. With kinetic simulations, spectral analysis of both HO2 and HCl, as well as the accurate line strength of the HCl R(9) transition at 3059.

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Toward a phylogenomic classification of magnoliids.

Am J Bot

January 2025

National Herbarium of NSW, Botanic Gardens of Sydney, Mount Annan, NSW, Australia.

Premise: Magnoliids are a strongly supported clade of angiosperms. Previous phylogenetic studies based primarily on analyses of a limited number of mostly plastid markers have led to the current classification of magnoliids into four orders and 18 families. However, uncertainty remains regarding the placement of several families.

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Pulsed Dipolar ESR Spectroscopy (PDS) is a uniquely powerful technique to characterize the structural property of intrinsically disordered proteins (IDPs) and polymers and the conformational evolution of IDPs and polymers, e.g. during assembly, by offering the probability distribution of segment end-to-end distances.

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Design, optimization, and inference of biphasic decay of infectious virus particles.

J Theor Biol

January 2025

Department of Biology, University of Maryland, College Park, 20742, MD, USA; Institut de Biologie, Ecole Normale Superieure, Paris, 75005, France; School of Biological Sciences, Georgia Institute of Technology, Atlanta, 30332, GA, USA. Electronic address:

Virus population dynamics are driven by counter-balancing forces of production and loss. Whereas viral production arises from complex interactions with susceptible hosts, the loss of infectious virus particles is often approximated as a first-order kinetic process. As such, experimental protocols to measure infectious virus loss are not typically designed to identify non-exponential decay processes.

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Spontaneous coronary artery dissection is a rare cause of unstable angina, myocardial infarction, and sudden cardiac death, particularly among young women and individuals without conventional atherosclerotic risk factors. We present the case of a 43-year-old woman who had spontaneous coronary artery dissection involving the left main with extension to left anterior descending artery and left circumflex artery. She was ultimately managed medically, with a good outcome.

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