AI Article Synopsis
- The reaction of RSbO3H2 with t-butylsilanetriol results in the formation of organoantimony(v) molecular triangles, which are stabilized by siloxane structures.
- Depending on the specific reaction conditions and substituents on the antimony atom, different siloxane frameworks can form, including disiloxane-tetrasiloxane combinations or a trisiloxane framework.
- This process ultimately stabilizes the triangular structure of three antimony atoms (Sb3).
Article Abstract
The reaction of RSbO3H2 with t-butylsilanetriol has led to the isolation of organoantimony(v) based molecular triangles stabilized by siloxane frameworks. Depending on the reaction conditions employed or the substituents present on the antimony atom, either a combination of a disiloxane and a tetrasiloxane framework or a trisiloxane framework was generated in situ leading to the stabilization of the Sb3 triangle.
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| http://dx.doi.org/10.1039/c5dt01590a | DOI Listing |
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