Conditional reversibility in nonequilibrium stochastic systems.

Phys Rev E

Department of Chemistry and Biochemistry and Institute for Physical Science and Technology, University of Maryland, College Park, Maryland 20742, USA.

Published: February 2016

For discrete-state stochastic systems obeying Markovian dynamics, we establish the counterpart of the conditional reversibility theorem obtained by Gallavotti for deterministic systems [Ann. de l'Institut Henri Poincaré (A) 70, 429 (1999)]. Our result states that stochastic trajectories conditioned on opposite values of entropy production are related by time reversal, in the long-time limit. In other words, the probability of observing a particular sequence of events, given a long trajectory with a specified entropy production rate σ, is the same as the probability of observing the time-reversed sequence of events, given a trajectory conditioned on the opposite entropy production, -σ, where both trajectories are sampled from the same underlying Markov process. To obtain our result, we use an equivalence between conditioned ("microcanonical") and biased ("canonical") ensembles of nonequilibrium trajectories. We provide an example to illustrate our findings.

Download full-text PDF

Source
http://dx.doi.org/10.1103/PhysRevE.93.022101DOI Listing

Publication Analysis

Top Keywords

entropy production
12
conditional reversibility
8
stochastic systems
8
conditioned opposite
8
probability observing
8
sequence events
8
reversibility nonequilibrium
4
nonequilibrium stochastic
4
systems discrete-state
4
discrete-state stochastic
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!