We synthesized CuZr/Cu multilayers and performed nanoindentation testing to explore the dependence of plastic deformation modes on the thickness of CuZr layers. The Cu layers were 18 nm thick and the CuZr layers varied in thickness from 4 nm to 100 nm. We observed continuous plastic co-deformation in the 4 nm and 10 nm CuZr - 18 nm Cu multilayers and plastic-induced shear instability in thick CuZr layers (>20 nm). The plastic co-deformation is ascribed to the nucleation and interaction of shear transformation zones in CuZr layers at the adjacent interfaces, while the shear instability is associated with the nucleation and propagation of shear bands in CuZr layers. Shear bands are initialized in the CuZr layers due to the accumulated glide dislocations along CuZr-Cu interfaces, and propagate into adjacent Cu layers via slips on {111} plane non-parallel to the interface. Due to crystallographic constraint of the Cu layers, shear bands are approximately parallel to {111} plane in the Cu layer.
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http://dx.doi.org/10.1038/srep23306 | DOI Listing |
Materials (Basel)
February 2023
Key Laboratory of Advanced Structural Materials, Ministry of Education, Changchun University of Technology, Changchun 130012, China.
ACS Appl Mater Interfaces
September 2021
College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China.
Considering the abundance of iron and manganese within the Earth's crust, the cathode O3-NaFeMnO has shown great potential for large-scale energy storage. Following the strategy of introducing specific heteroelements to optimize the structural stability for energy storage, the work has obtained an O3-type NaFeMnCuZrO that exhibits enhanced electrochemical performance and air stability. It displays an initial reversible capacity of 147.
View Article and Find Full Text PDFJ Chem Phys
September 2020
Material Measurement Laboratory, Materials Science and Engineering Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA.
Recent studies of structural relaxation in Cu-Zr metallic glass materials having a range of compositions and over a wide range of temperatures and in crystalline UO under superionic conditions have indicated that the localization model (LM) can predict the structural relaxation time τ of these materials from the intermediate scattering function without any free parameters from the particle mean square displacement ⟨r⟩ at a caging time on the order of ps, i.e., the "Debye-Waller factor" (DWF).
View Article and Find Full Text PDFNanoscale Res Lett
August 2019
Department of Engineering Mechanics, Chongqing University, Chongqing, 400044, China.
B2 phase copper-zirconium (CuZr) particles are often used as an enhancement agent to improve the toughness of metallic glass; however, the orientation dependence of its phase transformation behaviors under loading remains unclear. In this work, molecular dynamics simulation of uniaxial tension and compression of B2 phase CuZr along different crystallographic orientation are performed to investigate the orientation-related mechanical response and phase transformation mechanisms. It was found that the mechanical behavior of CuZr exhibits obvious tension/compression asymmetry, but their failure mode is mainly local amorphization.
View Article and Find Full Text PDFPhys Chem Chem Phys
July 2019
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, Ministry of Education, Shandong University, Jinan 250061, People's Republic of China.
Despite the fact that its crystal state is thermodynamically stable, CuZr alloy is prone to form metastable glass at a high cooling rate. However, the confinement can induce nano-crystallization with a novel sandwich-like hierarchical structure consisting of pure Cu layers, pure Zr layers and mixed layers by conducting molecular dynamics simulations. The liquid-to-crystal transition temperature and interatomic repulsion softness display abnormal oscillations, instead of monotonous variation, as the wall-wall separation increases.
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