Atomic force microscopy-based nanoindentation is used to image and probe the local mechanical properties of thin disordered nanoparticle packings. The probed region is limited to the size of a few particles, and an individual particle can be loaded and displaced to a fraction of a single particle radius. The results demonstrate heterogeneous mechanical response that is location-dependent. The weak locations may be analogous to the "soft spots" previously predicted in glasses and other disordered packings.
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http://dx.doi.org/10.1021/acs.nanolett.5b05319 | DOI Listing |
Nat Commun
January 2025
School of Chemical and Biological Engineering, Institute of Chemical Processes, Seoul National University, Seoul, Republic of Korea.
Colloidal nanocrystals inherently undergo structural changes during chemical reactions. The robust structure-property relationships, originating from their nanoscale dimensions, underscore the significance of comprehending the dynamic structural behavior of nanocrystals in reactive chemical media. Moreover, the complexity and heterogeneity inherent in their atomic structures require tracking of structural transitions in individual nanocrystals at three-dimensional (3D) atomic resolution.
View Article and Find Full Text PDFLangmuir
January 2025
College of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550025, Guizhou, China.
LiFeMnPO (0 < < 1) has a high operating voltage range and theoretical energy density, but its actual capacity decreased due to its low electronic conductivity. To overcome this problem, we successfully prepared LiFeMnPO/C (LFMP/C) with a uniform carbon coating by a one-step solvothermal method using bamboo shavings as the carbon source. The results showed that heating at a reaction temperature of 180 °C for 18 h was the optimal synthesis condition to obtain LFMP/C.
View Article and Find Full Text PDFAcc Chem Res
January 2025
Institute of Energy: Sustainability, Environment and Equity (I:SEE), State University of New York at Stony Brook, Stony Brook, New York 11794, United States.
ConspectusLithium-ion batteries are recognized as an important electrochemical energy storage technology due to their superior volumetric and gravimetric energy densities. Graphite is widely used as the negative electrode, and its adoption enabled much of the modern portable electronics technology landscape. However, developing markets, such as electric vehicles and grid-scale storage, have increased demands, including higher energy content and a diverse materials supply chain.
View Article and Find Full Text PDFHydrothermal carbonization (HTC) of carbohydrates has been reported as a sustainable and green technique to produce carbonaceous micro- and nano-materials. These materials have been developed for several applications, including catalysis, separation science, metal ion adsorption and nanomedicine. Carbon nanoparticles (CNPs) obtained through HTC are particularly interesting for the latter application since they exhibit photothermal properties when irradiated with near-infrared (NIR) light, act as an antioxidant by scavenging reactive oxygen species (ROS), and present good colloidal stability and biocompatibility.
View Article and Find Full Text PDFChem Sci
January 2025
Department of Chemistry, The University of Adelaide Adelaide South Australia 5005 Australia
Singlet fission (SF) is a process that is potentially beneficial for photovoltaics by producing two triplet excitons from a single photon, but its application is often hindered by the inability to effectively separate the resultant triplet excitons. It has been proposed that an energy gradient can assist in separating triplet excitons through triplet energy transfer between chromophores of different triplet energies, but this approach has only been studied in solution and the efficacy of this strategy in the solid state is under explored. Here, we investigate energy-gradient-driven SF in a disordered solid state, in the form of suspensions of 5,12-bis(triisopropylsilylethnyl)tetracene:6,13-bis(triisopropylsilylethnyl)pentance (TIPS-Tn:TIPS-Pn) blend nanoparticles (NPs).
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