AI Article Synopsis
- A new compound, KH[(CH3)4N]3{[Re(CO)3]4[(μ2-OH)(μ3-O)(W5O18)]}·6H2O, has been created and analyzed as a unique isopentatungstate-supported metal carbonyl derivative.
- This compound is notable for its efficiency in catalyzing the epoxidation of cyclooctene using H2O2, achieving a high conversion rate of 98.9% and selectivity of 99%.
- Additionally, the study examined the compound's behavior in solution using electrospray ionization mass spectrometry to understand its properties better.
Article Abstract
A novel isopentatungstate-supported metal carbonyl derivative KH[(CH3)4N]3{[Re(CO)3]4[(μ2-OH)(μ3-O)(W5O18)]}·6H2O () has been synthesized and characterized. Compound represents the second example of isopolyoxotungstate-supported metal carbonyl derivative. The catalysis of for alkene epoxidation with H2O2 was investigated, and was found to efficiently catalyze the epoxidation of cyclooctene with high conversion (98.9%) and excellent selectivity (99%). Furthermore, the solution behavior of the polyanion was also explored using electrospray ionization mass spectrometry.
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