To meet the ever-increasing requirements for the next generation of sustainable and versatile energy-related devices, conjugated polymers, which have potential advantages over small molecules and inorganic materials, are among the most promising types of green candidates. The properties of conjugated polymers can be tuned through modification of the structure and incorporation of different functional moieties. In addition, superior performances can be achieved as a result of the advantages of nanostructures, such as their large surface areas and the shortened pathways for charge transfer. Therefore, nanostructured conjugated polymers with different properties can be obtained to be applied in different energy-related organic devices. This review focuses on the application and performance of the recently reported nanostructured conjugated polymers for high-performance devices, including rechargeable lithium batteries, microbial fuel cells (MFCs), thermoelectric generators, and photocatalytic systems. The design strategies, reaction mechanisms, advantages, and limitations of nanostructured conjugated polymers are further discussed in each section. Finally, possible routes to improve the performances of the current systems are also included in the conclusion.
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http://dx.doi.org/10.1002/asia.201600293 | DOI Listing |
Analyst
January 2025
Guangdong Provincial Key Laboratory of Electronic Functional Materials and Devices, Huizhou University, Huizhou, 516007, China.
Disordered polymerization of polymers widens the polymerization degree distribution, which leads to uncontrollable thickness and significantly weakens their sensing performance. Herein, poly(sodium -styrenesulfonate)-functionalized reduced graphene oxide (PSS-rGO) with multichannel chain structures coated with thin polyaniline layer (PSS-rGO/PANI) nanocomposites was synthesized a facile interfacial polymerization route. The morphology and microstructure of the PSS-rGO/PANI nanocomposites were characterized using Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM).
View Article and Find Full Text PDFACS Nano
January 2025
Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123, China.
Molecular-scale electronics focuses on understanding and utilizing charge transport through individual molecules. A key issue is the charge transport capability of a single molecule characterized by current decay. We visualize the on-site formation of conjugated polymers with varying carbon-carbon bond orders by using scanning tunneling microscopy and noncontact atomic force microscopy.
View Article and Find Full Text PDFJ Nanobiotechnology
January 2025
State Key Laboratory of Molecular Engineering of Polymers, Fudan University, Shanghai, 200438, China.
Background: Intraoperative imaging is critical for achieving precise cancer resection. Among available techniques, Raman spectral imaging emerges as a promising modality due to its high spatial resolution and signal stability. However, its clinical application for in vivo imaging is limited by the inherently weak Raman scattering signal.
View Article and Find Full Text PDFChemSusChem
January 2025
Yonsei University, School of Integrated Technology (SIT), Yonsei Institute of Convergence Technology (YICT), 85 Songdogwahak-ro, 21983, Yeonsu-gu, KOREA, REPUBLIC OF.
Poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) based electrolyte is a promising alternative to liquid electrolytes in lithium metal batteries. However, its commercial application is limited by high crystallinity and low Li+ ion conductivity. In this study, we synthesized a fluorinated Li-based metal-organic framework (Li-MOF-F) and used it as a filler to address these limitations.
View Article and Find Full Text PDFBiomaterials
January 2025
Shanghai Key Laboratory of Functional Materials Chemistry, East China University of Science and Technology, Shanghai, 200237, China. Electronic address:
Fluorescence imaging in the second near-infrared window (NIR-II) has shown tremendous potential for in vivo monitoring of biological processes, offering high spatial resolution and real-time imaging capabilities. Conjugated polymers, commonly used as photothermal agents (PTAs) in photothermal therapy, have emerged as promising candidates for NIR-II imaging. However, their imaging efficiency is compromised by aggregation, which arises from strong π-π stacking interactions between their extended π-conjugated backbones.
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