Reactions of [Ce(IV)(LOEt)2Cl2] (LOEt(-) = [Co(η(5)-C5H5){P(O)(OEt)2}3](-)) and [Ce(μ-O){N(Pr(i)2PO)2}4Cl2] with PhIO afford the λ3-iodane complexes [Ce(IV)(LOEt)2{OI(Cl)Ph}2] and [Ce{N(Pr(i)2PO)2}3{OI(Cl)Ph}], respectively, whereas that between [Ce(IV)(LOEt)2Cl2] and PhIO2 or excess PhIO yields the λ5-iodane adduct [Ce(IV)(LOEt)2{OI(O)ClPh}2]. The crystal structures of the Ce(IV)λ3- and λ5-iodane complexes have been determined and their oxo transfer reactivities have been investigated.
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Reduction of hypervalent iodine by coordination to iron(iii) and the crystal structures of PhIO and PhIO.
Dalton Trans
November 2016
Department of Physics, Chemistry and Pharmacy, University of Southern Denmark, Campusvej 55, 5230 Odense M, Denmark.
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- The iodine L-edge X-ray Absorption Near Edge Structure (XANES) helps assess oxidation states of iodine compounds, showing a range from -1 to +7 with corresponding edge energies.
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Iodosylbenzene and iodylbenzene adducts of cerium(IV) complexes bearing chelating oxygen ligands.
Dalton Trans
April 2016
Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, People's Republic of China.
Reactions of [Ce(IV)(LOEt)2Cl2] (LOEt(-) = [Co(η(5)-C5H5){P(O)(OEt)2}3](-)) and [Ce(μ-O){N(Pr(i)2PO)2}4Cl2] with PhIO afford the λ3-iodane complexes [Ce(IV)(LOEt)2{OI(Cl)Ph}2] and [Ce{N(Pr(i)2PO)2}3{OI(Cl)Ph}], respectively, whereas that between [Ce(IV)(LOEt)2Cl2] and PhIO2 or excess PhIO yields the λ5-iodane adduct [Ce(IV)(LOEt)2{OI(O)ClPh}2]. The crystal structures of the Ce(IV)λ3- and λ5-iodane complexes have been determined and their oxo transfer reactivities have been investigated.
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Arzneimittelforschung
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Laboratoire de Chimie Organique, Faculté de Pharmacie de Lyon, France.
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