The Cu4I4-MOF-based mixed matrix membranes (MMMs) can be readily prepared by one-step in situ self-assembly of a tri-armed oxadiazole-bridged ligand and CuI in polymer binder solution under ambient conditions. The visual and luminescent HCl(g) sensing detecting limits of the resulting Cu4I4-MOF-based MMMs are 3.2 and 1.6 ppb, respectively, and the response time is less than 1 min.
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An in situ self-assembled Cu4I4-MOF-based mixed matrix membrane: a highly sensitive and selective naked-eye sensor for gaseous HCl.
Chem Commun (Camb)
April 2016
College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University, Jinan 250014, P. R. China.
The Cu4I4-MOF-based mixed matrix membranes (MMMs) can be readily prepared by one-step in situ self-assembly of a tri-armed oxadiazole-bridged ligand and CuI in polymer binder solution under ambient conditions. The visual and luminescent HCl(g) sensing detecting limits of the resulting Cu4I4-MOF-based MMMs are 3.2 and 1.
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