AI Article Synopsis
- The study introduces 3,4-dihydroxysalophen Schiff base (3,4-DHS) as a multifunctional ligand for synthesizing gold nanoparticles (AuNPs) with unique properties.
- 3,4-DHS can effectively reduce gold chloride (HAuCl4) in water and also functions as a stabilizing agent, leading to stable colloidal AuNPs with controlled sizes in a single reaction process.
- When applied to carbon electrodes, the 3,4-DHS-AuNPs demonstrate significant electrocatalytic activity for the oxidation of hydrazine and for the oxidation/reduction of hydrogen peroxide.
Article Abstract
Multi-tasking 3,4-dihydroxysalophen Schiff base tetradentate ligand (3,4-DHS) as reductant, stabilizer, and catalyst in a new concept of gold nanoparticles (AuNPs) synthesis is demonstrated. 3,4-DHS is able to reduce HAuCl4 in water, acting also as capping agent for the generation of stable colloidal suspensions of Schiff base ligand-AuNPs assemblies of controlled size by providing a robust coating to AuNPs, within a unique reaction step. Once deposited on carbon electrodes, 3,4-DHS-AuNPs assemblies show a potent electrocatalytic effect towards hydrazine oxidation and hydrogen peroxide oxidation/reduction.
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| http://dx.doi.org/10.1007/s00216-016-9329-y | DOI Listing |
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