Highly efficient P-I-N type perovskite/bulk-heterojunction (BHJ) integrated solar cells (ISCs) with enhanced fill factor (FF) (≈80%) and high near-infrared harvesting (>30%) are demonstrated by optimizing the BHJ morphology with a novel n-type polymer, N2200, and a new solvent-processing additive. This work proves the feasibility of highly efficient ISCs with panchromatic absorption as a new photovoltaic architecture and provides important design rules for optimizing ISCs.
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