Integration of electrochemical capacitors with silicon-based electronics is a major challenge, limiting energy storage on a chip. We describe a wafer-scale process for manufacturing strongly adhering carbide-derived carbon films and interdigitated micro-supercapacitors with embedded titanium carbide current collectors, fully compatible with current microfabrication and silicon-based device technology. Capacitance of those films reaches 410 farads per cubic centimeter/200 millifarads per square centimeter in aqueous electrolyte and 170 farads per cubic centimeter/85 millifarads per square centimeter in organic electrolyte. We also demonstrate preparation of self-supported, mechanically stable, micrometer-thick porous carbon films with a Young's modulus of 14.5 gigapascals, with the possibility of further transfer onto flexible substrates. These materials are interesting for applications in structural energy storage, tribology, and gas separation.
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http://dx.doi.org/10.1126/science.aad3345 | DOI Listing |
Int J Biol Macromol
January 2025
College of Ocean Food and Biological Engineering, Jimei University, Xiamen 361021, China. Electronic address:
Purple passion fruit peel (PPFP) is a common biomass waste. Meanwhile, hydrothermal carbonization (HTC) is a common technology used for thermal conversion of biomass waste. Herein, the aqueous phase (AP) of PPFP was determined using HTC, and its properties were studied.
View Article and Find Full Text PDFACS Electrochem
January 2025
Department of Chemistry, Texas A&M University, College Station, Texas 77843, United States.
We demonstrate the application and benefit of optically transparent carbon electrodes (OTCEs) for single entity nanoelectrochemistry. OTCEs are prepared by pyrolyzing thin photoresist films on fused quartz coverslips to create conductive, transparent, thin films. Optical, electrical, topographical, and electrochemical properties of OTCEs are characterized to evaluate their suitability for single entity electrochemistry.
View Article and Find Full Text PDFFront Bioeng Biotechnol
January 2025
Department of Orthodontics, Shanghai Ninth People's Hospital, Shanghai Jiao Tong University School of Medicine, College of Stomatology, Shanghai Jiao Tong University, National Center for Stomatology, National Clinical Research Center for Oral Diseases, Shanghai Key Laboratory of Stomatology and Shanghai Research Institute of Stomatology, Research Unit of Oral and Maxillofacial Regenerative Medicine, Chinese Academy of Medical Sciences, Shanghai, China.
A one-step hydrothermal method was applied to prepare carbon dots (CDs) with superior fluorescence properties using chitosan as a carbon source. The as-prepared carbon dots were then grafted onto a sodium alginate-gelatin hydrogel film to form a fluorescent hydrogel film (FHGF), emitting at 450 nm under excitation of 350 nm light. In comparison to the CDs, the fluorescence intensity of this film was maintained over 90.
View Article and Find Full Text PDFMater Horiz
January 2025
State Key Laboratory of Organic-Inorganic Composites, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China.
Solar energy sources have garnered significant attention as a renewable energy option. Despite this, the practical power conversion efficiency (PCE) of widely used silicon-based solar cells remains low due to inefficient light utilization. In this study, carbon dots (APCDs) were prepared a hydrothermal method using ammonium polyphosphate and -phenylenediamine, then incorporated into a silicone-acrylic emulsion (CAS) to create a luminescent down-shifting (LDS) layer for solar cells.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Department of Chemical Engineering, Arak University, Arak, Iran. Electronic address:
Polysaccharides such as chitosan, alginate, cellulose, and carrageenan have emerged as promising adsorbents due to their biodegradability, abundant availability, and diverse chemical functionality. These biopolymers exhibit promising performance for adsorption of a wide range of pollutants including heavy metals (e.g.
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