Bismutite (Bi2O2CO3) possessing diverse morphologies, namely nanosheets, nanodiscs and nanoplatelets, was synthesized by a simple controllable method using bismuth nitrate pentahydrate and urea as precursors in a water/ethylene glycol mixture. The as-synthesized samples showed unique physical and chemical properties, such as varying morphology, phase identification, chemical composition, surface area and surface potential. Bi2O2CO3 nanosheets exhibited excellent adsorption capabilities for anionic dyes (acid orange 7 and methyl orange) and high photocatalytic performance for the decolorization of cationic dyes (rhodamine B and methylene blue) under simulated solar illumination. Furthermore, the electrochemical performance of Bi2O2CO3 nanosheets showed good capacitance properties and hence could be a potential candidate for electrode materials in energy related applications.
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http://dx.doi.org/10.1039/c5cp07523h | DOI Listing |
Adv Mater
December 2024
School of Materials Science and Engineering, Peking University, Beijing, 100871, P. R. China.
Renewable electricity-driven CO electroreduction provides a promising route toward carbon neutrality and sustainable chemical production. Nevertheless, the viability of this route faces constraints of catalytic efficiency and durability in near-neutral electrolytes at industrial-scale current densities, mechanistically originating from unfavorable accommodation of H species from water dissociation. Herein, a new strategy is reported to accelerate water dissociation by the rich surface hydroxyl on bismuth subcarbonate nanosheets in situ electrochemical transformed from bismuth hydroxide nanotube precursors.
View Article and Find Full Text PDFEnviron Res
January 2025
Xuefei Wang, Wuhan University of Technology, Wuhan, 430070, China. Electronic address:
The wastewater polluted by antibiotics is very harmful and dangerous since these contaminants are poisonous and cannot occur by self-degradation. Research has verified that photocatalytic degradation is an effective strategy for addressing this issue; thus, developing a promising photocatalyst is indispensable. In this work, BiO/BiOCO nanosheet heterojunctions were constructed with an in-situ growth method, and their structure-photocatalytic performance relationships in degrading tetracycline (TC) were elucidated in detail.
View Article and Find Full Text PDFChemSusChem
January 2025
State Key Laboratory of New Textile Materials and Advanced Processing Technologies, Wuhan Textile University, Wuhan, 430200, PR China.
The photocatalytic reduction of carbon dioxide (CO) has emerged as a compelling strategy for the conversion of renewable energy. However, the expeditious recombination of photogenerated charge carriers and the inadequate light absorption capabilities are currently predominant challenges. Herein, we developed a facile hydrothermal approach to synthesize a sulfur doped BiOCO nanosheet with a tunable energy band structure designed to enhance visible light absorption.
View Article and Find Full Text PDFAdv Healthc Mater
November 2024
Department of Medical Biochemistry and Molecular Biology, School of Medicine, Jinan University, Guangzhou, Guangdong, 510632, China.
Synergistic therapy has become the major therapeutic method for malignant tumors in clinical. Photodynamic therapy (PDT) and radiotherapy (RT) always combine together because of their identical anti-tumor mechanisms, that is reactive oxygen species are generated by the use of radiosensitizers after irradiation by X-ray to efficiently kill cancer cells, PDT also follows similar mechanism. Full exposure of energy-absorbing species in nanomaterials to X-ray or near-infrared light irradiation makes the energy interchange between nanomaterials and surrounding HO or dissolved oxygen easier, however, it remains challenging.
View Article and Find Full Text PDFSmall
August 2024
College of Materials Science and Engineering, Fuzhou University, New Campus, Minhou, Fujian, 350108, China.
A facile gaseous CO mediated solid-to-solid transformation principle is adopted to insert additional CO anions into the thin single-crystal nanosheets of BiOCO, which is built of periodic arrays of intrinsic CO anions and (BiO) layers. The additional CO anions create abundant defects. The BiOCO nanosheets with rich interlayer CO exhibit superior electronic properties and charge transfer kinetics than the pristine single-crystal 2D BiOCO and display enhanced catalytic activity in photocatalytic CO reduction reaction and the photocatalytic oxidative degradation of organic pollutants.
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