The Jahn-Teller distortion, by its very nature, is often at the heart of the various electronic properties displayed by perovskites and related materials. Despite the Jahn-Teller mode being nonpolar, we devise and demonstrate, in the present Letter, an electric field control of Jahn-Teller distortions in bulk perovskites. The electric field control is enabled through an anharmonic lattice mode coupling between the Jahn-Teller distortion and a polar mode. We confirm this coupling and quantify it through first-principles calculations. The coupling will always exist within the Pb2_{1}m space group, which is found to be the favored ground state for various perovskites under sufficient tensile epitaxial strain. Intriguingly, the calculations reveal that this mechanism is not only restricted to Jahn-Teller active systems, promising a general route to tune or induce novel electronic functionality in perovskites as a whole.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1103/PhysRevLett.116.057602 | DOI Listing |
Inorg Chem
December 2024
School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332, United States.
The interplay between quantum effects from magnetic frustration, low-dimensionality, spin-orbit coupling, and crystal electric field in rare-earth materials leads to nontrivial ground states with unusual magnetic excitations. Here, we investigate YbTaO, which hosts a buckled square net of Yb ions with = 1/2 moments. The observed Curie-Weiss temperature is about -1 K, implying an antiferromagnetic coupling between the Yb moments.
View Article and Find Full Text PDFJ Comput Biol
December 2024
Electrical, Computer and Biomedical Engineering, Toronto Metropolitan University, Toronto, Canada.
Image-to-image translation has gained popularity in the medical field to transform images from one domain to another. Medical image synthesis via domain transformation is advantageous in its ability to augment an image dataset where images for a given class are limited. From the learning perspective, this process contributes to the data-oriented robustness of the model by inherently broadening the model's exposure to more diverse visual data and enabling it to learn more generalized features.
View Article and Find Full Text PDFTomography
December 2024
Department of Electrical and Computer Engineering, University of Wisconsin-Madison, Madison, WI 53706, USA.
This research introduces BAE-ViT, a specialized vision transformer model developed for bone age estimation (BAE). This model is designed to efficiently merge image and sex data, a capability not present in traditional convolutional neural networks (CNNs). BAE-ViT employs a novel data fusion method to facilitate detailed interactions between visual and non-visual data by tokenizing non-visual information and concatenating all tokens (visual or non-visual) as the input to the model.
View Article and Find Full Text PDFTomography
November 2024
KYAMOS Ltd., 37 Polyneikis Street, Strovolos, Nicosia 2047, Cyprus.
: Accurate reconstruction of internal temperature fields from surface temperature data is critical for applications such as non-invasive thermal imaging, particularly in scenarios involving small temperature gradients, like those in the human body. : In this study, we employed 3D convolutional neural networks (CNNs) to predict internal temperature fields. The network's performance was evaluated under both ideal and non-ideal conditions, incorporating noise and background temperature variations.
View Article and Find Full Text PDFToxins (Basel)
December 2024
Department of Food Analysis and Nutrition, University of Chemistry and Technology, Prague, Technicka 3, 166 28 Prague, Czech Republic.
The increasing contamination of cereals by micromycetes and mycotoxins during malting still poses an unresolved food safety problem. This study characterises the potential of the novel, rapidly developing food production technology of Pulsed Electric Field (PEF) to reduce the viability of fungi and the production of mycotoxins during malting. Barley, artificially inoculated with four species, was treated by PEF with two different intensities and then malted using a standard Pilsner-type technology.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!