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Oxidation of cholesterol and O-protected derivatives by the environmental pollutant NO₂. | LitMetric
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Oxidation of cholesterol and O-protected derivatives by the environmental pollutant NO₂.

A N Zalewski J G Nathanael J M White U Wille

Chem Commun (Camb)

School of Chemistry, Bio21 Institute, The University of Melbourne, Parkville, Victoria 3010, Australia.

Published: March 2016

Exposure of O-protected and free cholesterol to NO2˙ under exclusion of water leads to nitroimine nitrates through a non-radical mechanism, which reveals the high susceptibility of the π system to oxidative damage. In the presence of moisture the reaction leads to 6-nitrocholesterols , which result from hydrolysis and oxidation of 2.

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 Source
http://dx.doi.org/10.1039/c5cc09663dDOI Listing

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