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Crystal structure of (tert-butyl-dimethyl-sil-yl)tri-phenyl-germane, Ph3Ge-SiMe2(t-Bu). | LitMetric

Crystal structure of (tert-butyl-dimethyl-sil-yl)tri-phenyl-germane, Ph3Ge-SiMe2(t-Bu).

Acta Crystallogr E Crystallogr Commun

A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova St. 28, 119991 Moscow, Russian Federation.

Published: December 2015

In the title compound, Ph3Ge-SiMe2(t-Bu) or C24H30GeSi, the Si and Ge atoms both possess a tetra-hedral coordination environment with C-E-C (E = Si, Ge) angles in the range 104.47 (5)-114.67 (5)°. The mol-ecule adopts an eclipsed conformation, with three torsion angles less than 29.5°. In the crystal, neighbouring mol-ecules are combined to dimers by six T-shaped C-H⋯π inter-actions, forming sixfold phenyl embraces (6PE).

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4719953PMC
http://dx.doi.org/10.1107/S2056989015022872DOI Listing

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