We report a unique intercluster compound comprising a Ag41 cage encapsulating a divacant [α-SiW(10)O37](10-) anion and a complete [β-SiW(12)O40](4-) anion as a counteranion. Two electro-redox centers associated with the inner and outer POM anions show interesting electrochemical behaviours, because the stable Ag41 cage acts as an electron transfer mediator.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c6cc00524a | DOI Listing |
Publication Analysis
Top Keywords
intercluster compound
8
ag41 cage
8
transformation polyoxometalates
4
polyoxometalates formation
4
formation intercluster
4
compound [ag41α-siw10o37tbuc≡c27ch3cn3][β-siw12o40]
4
[ag41α-siw10o37tbuc≡c27ch3cn3][β-siw12o40] report
4
report unique
4
unique intercluster
4
compound comprising
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!