AI Article Synopsis
- The researchers created Ni(II) and Al(III) 10-azacorroles by using nitrogen-bridged bisdipyrrins in a coordination-induced cyclization process.
- Al(III) 10-azacorrole showed different optoelectronic properties compared to Ni(II) 10-azacorrole.
- This difference highlights how the azacorrole ligand affects electronic behavior differently than porphyrin does.
Article Abstract
We have synthesized Ni(II) and Al(III) 10-azacorroles through coordination-induced cyclisation of nitrogen-bridged bisdipyrrins. Al(III) 10-azacorrole displayed contrasting optoelectronic behaviours from Ni(II) 10-azacorrole, underlining the different electronic effects of the azacorrole ligand from the porphyrin.
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| http://dx.doi.org/10.1039/c5cc10247b | DOI Listing |
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