In this work, we present a study of the nonlinear absorption properties from different gold nanorod (NR) systems in aqueous suspension. The NRs were obtained with the bottom-up protocol by the seed-mediated growth method (SMG), using Ag(+) ions at different concentrations, and CTAB as surfactant. By using this method, aspect ratios between 2 and 5 were obtained. The transverse surface plasmons (TSP) are located between 514 - 535 nm, while the longitudinal surface plasmons (LSP) are between 639 - 921 nm, for the different samples studied. The Z-scan technique was implemented for open (OA) and closed (CA) aperture at 532 and 1064 nm, with laser pulses of 26 ps, for vertical and horizontal polarizations, with respect to the incidence plane (horizontal). At 532 nm all samples showed saturable absorption (SA), while for samples with LSP near 1064 nm, such effect was observed only at low-energy pulse experimental conditions. In the high-energy pulse regime, an apparent reverse-saturable absorption (RSA) was observed for both wavelengths. However for 532 nm, it was possible to determine that this effect results from structural changes in the samples, which are manifested through the behavior of nonlinear absorption and refraction curves. These results were used to determine the irradiances to which NRs can be modified by photodegradation.
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http://dx.doi.org/10.1364/OE.24.00A154 | DOI Listing |
Nanophotonics
November 2024
Department of Physics, Shanghai University, Shanghai 200444, China.
Optical logic gates based on nonlinear optical property of material with ultrafast response speed and excellent computational processing power can break the performance bottleneck of electronic transistors. As one of the layered 2D materials, TaNiS exhibits high anisotropic mobility, exotic electrical response, and intriguing optical properties. Due to the low-symmetrical crystal structures, it possesses in-plane anisotropic physical properties.
View Article and Find Full Text PDFJ Phys Chem B
October 2024
Department of Chemistry and Chemical Biology, Indian Institute of Technology (Indian School of Mines) Dhanbad, Dhanbad826004, Jharkhand, India.
Three novel core green fluorescent protein (GFP) chromophore analogues, based on a doubly locked conformation and variable electronic effects by replacing one hydrogen with bromine, iodine, and methyl, respectively, have been synthesized to modulate the push-pull effect. These chromophores exhibited intramolecular H-bonding, as evidenced by single-crystal X-ray and H NMR studies. The fluorescence quantum yields (ϕ) of all of the chromophores were found to be more than an order of magnitude higher (∼0.
View Article and Find Full Text PDFNanomaterials (Basel)
October 2024
Laser Institute for Research and Applications LIRA, Beni-Suef University, Beni-Suef 62511, Egypt.
In this work, the nonlinear optical (NLO) properties of CuO nanoparticles (CuO NPs) were studied experimentally using the pulsed laser ablation (PLA) technique. A nanosecond Nd: YAG laser was employed as the ablation excitation source to create CuO NPs in distilled water. Various CuO NPs samples were prepared at ablation periods of 20, 30, and 40 min.
View Article and Find Full Text PDFACS Nano
November 2024
Shaanxi Joint Laboratory of Graphene, State Key Laboratory of Photon-Technology in Western China Energy, International Collaborative Center on Photoelectric Technology and Nano Functional Materials, Institute of Photonics & Photon-Technology, School of Physics, Northwest University, Xi'an 710069, China.
Ultrafast charge transfer in van der Waals heterostructures can effectively engineer the optical and electrical properties of two-dimensional semiconductors for designing photonic and optoelectronic devices. However, the nonlinear absorption conversion dynamics with the pump intensity and the underlying physical mechanisms in a type-II heterostructure remain largely unexplored, yet hold considerable potential for all-optical logic gates. Herein, two-dimensional ReSe/ReS heterostructure is designed to realize an unusual transition from reverse saturable absorption to saturable absorption (SA) with a conversion pump intensity threshold of approximately 170 GW/cm.
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