The role of protonated cyclopropane (PCP(+)) structures in carbocation rearrangement is a decades-old topic that continues to confound. Here, quantum-chemical computations (PBE molecular dynamics, PBE and CCSD optimizations, CCSD(T) energies) are used to resolve the issue. PCP(+) intermediates are neither edge-protonated nor corner-protonated (normally) but possess "closed" structures mesomeric between these two. An updated mechanism for hexyl ion rearrangement is presented and shown to resolve past mysteries from isotope-labeling experiments. A new table of elementary-step barrier heights is provided. The mechanism and barrier heights should be useful in understanding and predicting product distributions in organic reactions, including petroleum modification.
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| http://dx.doi.org/10.1021/acs.joc.5b02553 | DOI Listing |
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