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Molecular titanium-hydroxamate complexes as models for TiO2 surface binding. | LitMetric
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Molecular titanium-hydroxamate complexes as models for TiO2 surface binding.

Bradley J Brennan Jeffrey Chen Benjamin Rudshteyn Subhajyoti Chaudhuri Brandon Q Mercado Victor S Batista Robert H Crabtree Gary W Brudvig

Chem Commun (Camb)

Energy Sciences Institute and Department of Chemistry, Yale University, New Haven, Connecticut 06520, USA.

Published: February 2016

Hydroxamate binding modes and protonation states have yet to be conclusively determined. Molecular titanium(iv) phenylhydroxamate complexes were synthesized as structural and spectroscopic models, and compared to functionalized TiO2 nanoparticles. In a combined experimental-theoretical study, we find that the predominant binding form is monodeprotonated, with evidence for the chelate mode.

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http://dx.doi.org/10.1039/c5cc09857bDOI Listing

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