The characterization of new materials thermoluminescent used in radiation dosimetry, require the determination of kinetic parameters, which are associated with the number and shape of the peaks which presents its glow curve, among the most important are: the activation energy, E, or depth of the traps, the frequency factor, s, and the kinetics order, b. These parameters are necessary to predict the stability of thermoluminescent information after irradiation of the material. In this work, we present the results obtained for the determination of kinetic parameters of Tm-doped CaF, the methods used for the determination of kinetic parameters were; initial growth signal TL, General order Chen method, and Deconvolution of glow curve. The results showed that the glow curve of CaF presents three glow peaks, 492K main peak and two smaller peaks, one at 430K and another to 566K. The dosimetric glow peak fits to the general-order kinetics model.
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http://dx.doi.org/10.1016/j.apradiso.2015.12.060 | DOI Listing |
Sci Rep
January 2025
Amity Institute of Environmental Sciences (AIES), Amity University Uttar Pradesh (AUUP), Sector-125, Gautam Budh Nagar, Noida, 201313, India.
This study focused on simulating the adsorption-based separation of Methylene Blue (MB) dye utilising Oryza sativa straw biomass (OSSB). Three distinct modelling approaches were employed: artificial neural networks (ANN), adaptive neuro-fuzzy inference systems (ANFIS), and response surface methodology (RSM). To evaluate the adsorbent's potential, assessments were conducted using Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM).
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January 2025
Thermal and Energetic Systems Studies Laboratory (LESTE), LR99ES31, College of Engineering, University of Monastir, 5000, Monastir, Tunisia.
Using the RANS approach with the standard k-ω turbulence model, this study offers a novel investigation into the dynamic and thermal properties of turbulent impinging jet arrays. Our study examines the combined effect of the number of jets (N) and the jet-jet spacing (S) on flow mechanisms and heat transfer performance, which is unique compared to previous research that frequently focuses on the individual effects of parameters. Through the investigation of the turbulent kinetic energy, friction coefficient, velocity contours, streamlines, pressure contours, and local and mean Nusselt numbers, we provide important information about how these parameters impact flow dynamics.
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January 2025
Department of Civil and Environmental Engineering, Indian Institute of Technology Patna, Bihar - 801 106, India. Electronic address:
Perfluorooctanoic acid (PFOA) removal has gained significant attention due to its environmental stability and potential toxicity. This study aims to synthesize a chitosan-modified magnetic biochar (CS_MBC) for efficient PFOA removal from aqueous solutions. Various CS loading ratios (0.
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January 2025
Department of Civil and Environmental Engineering, University of Florence, Via di S. Marta, 3, 50139, Firenze, Italy.
The performance of Upflow Anaerobic Sludge Blanket (UASB) bioreactors treating sulfate (SO) -rich effluents depends on multiple factors, including microbial interactions and operational conditions. The high complexity of these systems necessitates the use of mathematical modelling tools to better understand the process and predict the long-term impacts of various operational variables. In this work, a mathematical model describing the long-term operation of a sulfate-fed 2.
View Article and Find Full Text PDFEnviron Monit Assess
January 2025
Department of Botany, Bacha Khan University, Charsadda, Charsadda, 24420, Khyber Pakhtunkhwa, Pakistan.
Wastewater is commonly contaminated with many pharmaceutical pollutants, so an efficient purification method is required for their removal from wastewater. In this regard, an innovative tertiary Se/SnO@CMC/Fe-GA nanocomposite was synthesized through encapsulation of metal organic frameworks (Fe-glutaric acid) onto Se/SnO-embedded-sodium carboxy methyl cellulose matrix to thoroughly evaluate its effectiveness for adsorption of levofloxacin drug from wastewater. The prepared Se/SnO@CMC/Fe-GA nanocomposite was analyzed via UV-Vis spectroscopy, Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), thermo gravimetric analysis (TGA), energy dispersive X-ray (EDX), and X-ray diffraction (XRD) to valuate optical property, size, morphology, thermal stability, and chemical composition.
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