We have developed a one-pot iron-catalysed sequential reaction of secondary amines with primary alcohols, trimethylsilyl cyanide and TBHP under mild reaction conditions to give the corresponding α-aminonitriles.
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An iron-catalysed allylation of organomagnesium reagents (alkyl, aryl) with simple allyl acetates proceeds under mild conditions (Fe(OAc) or Fe(acac), EtO, r.t.) to furnish various alkene and styrene derivatives.
View Article and Find Full Text PDFIron-catalysed sequential reaction towards α-aminonitriles from secondary amines, primary alcohols and trimethylsilyl cyanide.
Chem Commun (Camb)
February 2016
School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400030, China. and State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China.
We have developed a one-pot iron-catalysed sequential reaction of secondary amines with primary alcohols, trimethylsilyl cyanide and TBHP under mild reaction conditions to give the corresponding α-aminonitriles.
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