Li(+) Catalysis and Other New Methodologies for the Radical Polymerization of Less Activated Olefins.

Chem Rev

Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309-0215, United States.

Published: February 2016

After a brief survey of conventional radical polymerization of alkenes, we review their Li(+) catalyzed radical polymerization and their controlled radical polymerization. Emphasis is on homopolymerization, but related copolymerization of less activated monomers is mentioned as well.

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http://dx.doi.org/10.1021/acs.chemrev.5b00485DOI Listing

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